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CHEM 415, Atmospheric Chemistry Problem…
5
atmospheric chemistry
could anyone answer these questions?
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xxxx 415 xxxxxxx Set x
xxx
a.
b.
At [M] >> x (high pressure limit), xxx xxxxxxxxxx xxx
At xxx x x (low xxxxxxxx xxxxxxxx
xxx
xxx
xx x = x atm:
xxx
a.
xxx
Reactions 1 and 3 xxxx the catalytic xxxxx xxx O3 loss.
b. xxxxxxxx x xx xxx xxxx limiting step.
c.
xxxxxxx xxx derivation below.)
xxxxx = 50 pptv = xx x xxxxxxx x 1019 molecules cm-3) x 1.5 x 109 xxxxxxxxx cm-3
Converting in days:
Ozone xxxx xx xxxxxxxx in a few days.
d.
a. x xxxx xxxxxxxxxxxxx of HBr and HOBr xxxxx that xxx xxxxx xxx need xx xx formed xxxx the xxxxxxxx xx Br with xxxxxx
b.
xxxxx x xxxxxx x xxxxx x [BrO] x xxxx x xx xxxx = 50 x 10-12(3 x 1019 xxxxxxxxx xxxxx
= 1.5 x xxx xxxxxxxxx cm-3
xxxxxx x 10 pptv = 10 x xxxxxxx x 1019 xxxxxxxxx cm-3) = x x xxx xxxxxxxxx xxxx
xxxx = 40 ppb x 40 x xxxxxx x xxxx xxxxxxxxx xxxxx x 1.2 x xxxx xxxxxxxxx cm-3
xxxxxxx the xxxxxxxxx xxxxxxxxx
x[BrO]2 x x[BrO] x C x xx
where:
x x xxx x xxxxx
x = 2.55
[BrO] x 5.9 x 108 molecules xxxx
?? EMBED xxxxxxxxxx
xxxxxx x xxx x 108 xxxxxxxxx xxxx
[Br] = xxx x 105 molecules xxxx
[HBr] x 2.0 x xxx molecules cm-3
c. xxx two xxxxxxxxx xxxxxxxx xx xxxxx reacts xxxx ozone.
Br
xxx
O3
xx
HOBr
xx
HBr
xxxx
xxx
OH
xx
Total xxxxxxxx xx x
xxx
xxx xxxxx Equation.3 ???
xxxxxxxxxxxxxxxxxxx
_1462668445.unknown
xxxxxxxxxxxxxxxxxxx
xxxxxxxxxxxxxxxxxxx
xxxxxxxxxxxxxxxxxxx
xxxxxxxxxxxxxxxxxxx
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